1980 •
Electronic and Resonance Raman Spectra of Some New Mixed-Valence Compounds of Pt and Pd with a Metal-Halide Chain
Authors: G. C. Papavassiliou, D. Layek
Venue: Zeitschrift für Naturforschung B
Type: Publication
Abstract: Abstract The electronic and resonance Raman spectra of new mixed-valence compounds of the type M2ʹ[M(L)X3][M(L)X5], where Mʹ = K, NH4, M = Pt or Pd, L = NH3 or pyridine, and X = Cl, Br or I, have been studied. The single-crystal polarized reflectance spectra indicate the one-dimensional semiconductor behaviour. The polarized resonance Raman spectra confirm the --M(II)--X-M(IV)-X linear chain structure, which is in accordance with the X-ray results. The polarization of M-N bands can be explained by the Snyder's theory (1971).
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