BIP! Finder - Optical Properties of Halogen-Bridged Mixed-Valance Complexes, [M(en)2][PtX2(en)2](ClO4)4, (M=Pt, Pd and Ni; X=Cl, Br and I): Effects of Metal-Alternation

1989 • Optical Properties of Halogen-Bridged Mixed-Valance Complexes, [M(en)2][PtX2(en)2](ClO4)4, (M=Pt, Pd and Ni; X=Cl, Br and I): Effects of Metal-Alternation

Authors: Masahiro Yamashita; Koshiro Toriumi; Yoshiki Wada; Tadaoki Mitami

Venue: Journal of the Physical Society of Japan

Type: Publication

Abstract: The effect of metal alternation (Pt and M) in linear-chain halogen-bridged mixed-valence complexes, [M(en) 2 ][PtX 2 (en) 2 ](ClO 4 ) 4 , (X=Cl, Br and I; M=Pt, Pd and Ni; en=ethylenediamine), has been investigated using polarized reflection measurements. The electronic absorption spectra of these materials, obtained by applying the Kramers-Kronig relation to the reflectivity data, show two distinctive charge-transfer exciton bands associated with the inter-metal transitions, “M–Pt”, and the transitions from halogen ions to metal ions, �... (read more)

Impact:

1.3451036E-9 8.868664E-9 55 14

/ Attention: 0 3

Topics: Crystallography Atomic physics Molecular physics

DOI: 10.1143/jpsj.58.3013

External links: Crossref OpenAIRE

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