BIP! Finder - Bis[tris(3-tert-butyl-5-methylpyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate

2009 • Bis[tris(3-tert-butyl-5-methylpyrazol-1-yl)hydridoborato]ytterbium(II) toluene solvate

Authors: Josef Takats; Michael J. Ferguson; Kuburat Saliu

Venue: Acta Crystallographica Section E Structure Reports Online

Type: Publication

Abstract: In the title compound, [Yb(C24H40BN6)2]·C7H8, the Yb atom is coordinated by two tris(3-tert-butyl-5-methylpyrazol-1-yl)hydridoborate [TptBu,Me] ligands. One ligand binds in the κ3mode, throuh three N atoms of the pyrazolyl rings, the other ligand coordinates through two N atoms of the pyrazolyl rings and the H atom attached to the central Bviaan agostic-type interaction through the B—H group of the second TptBu,Meligand, giving an overall distorted octahedral geometry. One of thetert-butyl groups is disordered over two sites, with occupanci... (read more)

Topics: Crystallography Medicinal chemistry Stereochemistry

DOI: 10.1107/s1600536809017152

BIP! social metrics: 0 10
External links: Crossref OpenAIRE

Related works: Dataset 1

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