BIP! Finder - Optical properties of [M(L–L)2M(L–L)2X2](ClO4)4, (M = Pt, Pd; L–L = 1,2-diaminoethane or 1,2-diaminopropane; X = Cl, Br, I): bulk and small particles

1980 • Optical properties of [M(L–L)2M(L–L)2X2](ClO4)4, (M = Pt, Pd; L–L = 1,2-diaminoethane or 1,2-diaminopropane; X = Cl, Br, I): bulk and small particles

Authors: George C. Papavassiliou, Aristides D. Zdetsis

Venue: J. Chem. Soc., Faraday Trans. 2

Type: Publication

Abstract: The optical absorption and scattering spectra of small particles of [M(L–L)2M(L–L)2X2](ClO4)4, deposited on quartz plates or suspended in CCl4, have been studied. We found that the position of the maxima in the spectra depends on the size and shape of the particles. The peak positions of small spheres and small needles occur, respectively, at shorter and longer wavelengths than the peak position of the single-crystal reflectance spectrum. In the case of [Pt(dapn)2Pt(dapn)2I2](ClO4)4, for example, we found peaks at 730 (spheres), 975 (needle... (read more)

Topics: Atomic physics Molecular physics Optics

DOI: 10.1039/f29807600104

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