Abstract: Abstract Resonance Raman scattering, infrared luminescence and absorption spectra of [Pt(en) 2 ][Pt(en) 2 Cl 2 ](ClO 4 ) 4 single crystals have been measured for polarized light at 2 K and room temperature. Contrary to the previous works on polycrystals, the incident photon energy dependence of the Raman cross section due to the symmetric ClPt IV Cl stretching mode has a resonance peak at the charge-transfer absorption edge, which is well explained with the two-band model in a one-dimensional system. Two characteristic structures observed below...
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Topics:
Molecular physics
Atomic physics