BIP! Finder - The red and near-infrared resonance Raman spectroscopy of photo-induced defects in the mixed-valence linear chain complex [PtII(en)2][PtIV(en)2Cl2][ClO4]4

1990 • The red and near-infrared resonance Raman spectroscopy of photo-induced defects in the mixed-valence linear chain complex [PtII(en)2][PtIV(en)2Cl2][ClO4]4

Authors: Robert J. Donohoe, R. Brian Dyer, Basil I. Swanson

Venue: Solid State Communications

Type: Publication

Abstract: Abstract Resonance Raman (RR) spectra of the quasi-one-dimensional solid [PtII(en)2][PtIV(en)2Cl2][ClO4]4 were obtained wth red excitations (1.65 and 1.41 eV) as a function of photolysis of the solid with energy within the intervalence charge transfer band (2.41 eV). The 1.65 eV excitation corresponds to a polaronic local gap absorption which is known to increase in intensity upon photolysis [S. Kurita & M. Haruki, Synthetic Metals 29, F129 (1989)]. However, the RR spectrum which best reveals the photo-induced defects is obtained with 1.41 eV e... (read more)

Topics: Atomic physics Molecular physics

DOI: 10.1016/0038-1098(90)90376-m

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