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2018 • Halterman Corroles and Their Use as a Probe of the Conformational Dynamics of the Inherently Chiral Copper Corrole Chromophore

Authors: Kolle E. Thomas, Laura J. McCormick, Daniel Carrié, Hugo Vazquez-Lima, Gérard Simonneaux, Abhik Ghosh

Abstract: © 2018 American Chemical Society. Halterman corroles have been synthesized for the first time from pyrrole and Halterman's aldehyde via Gryko's "water-methanol method". These were derivatized to the corresponding copper complexes and subsequently to the β-octabromo complexes. Electronic circular dichroism spectra were recorded for the enantiopure copper complexes, affording the first such measurements for the inherently chiral Cu corrole chromophore. Interestingly, for a given configuration of the Halterman substituents, X-ray crystallographi (...) (Read More)

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Halterman Corroles and Their Use as a Probe of the Conformational Dynamics of the Inherent (...)

Kolle E. Thomas, Laura J. McCormick, Daniel Carrié, Hugo Vazquez-Lima, Gérard Simonneaux, Abhik Gh (...)

Inorganic Chemistry · 2018

Crystallography | Photochemistry | Stereochemistry |

Open Access

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