1990 •
Electric-field effects on the charge-transfer excitation in quasi-one-dimensional halogen-bridged mixed-valence Pt complexes: [Pt(ethylenediamine)2] [Pt(ethylenediamine)2X2](ClO4)4(X=Cl,Br,I)
Authors: Yoshiki Wada, Masahiro Yamashita
Venue: Physical Review B
Type: Publication
Abstract: Mesure du spectre d'electroreflexion. Le champ electrique induit de nouvelles bandes d'absorption pouvant etre attribuees aux excitons du transfert de charge interdit qui sont pairs. Ces excitons sont situes a une energie legerement superieure a celle des excitons impairs optiquement autorises. Le mecanisme de modulation peut etre quantitativement explique par le melange induit par champ electrique entre les excitons pairs et impairs. Determination des separations d'energie entre les excitons pairs et impairs
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