Abstract: Degassing of CO2 and precipitation of calcite to the surface of stalagmites can strongly impact isotope signals imprinted into the calcite of these speleothems. Here, we show that in all the variety of conditions occurring in nature only two distinct types of degassing exist. First, when a thin film of calcareous solution comes in contact to cave air lower pCO2 value than that of the aqueous CO2 in the water, molecular CO2 escapes by physical diffusion in several seconds. In a next step lasting several ten seconds, pH and DIC in the solution ac...
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Topics: 
Mineralogy
Geochemistry